This technique is typically used for electroless plating of nickel, silver, gold and copper. Vertical electroless copper metallization macdermid. The choice of ph for copper plating is very critical. Prior to introduction to eld process, the pet surface was plasmapretreated in argon atmosphere. Chapter electroless copper in printed wiring board fabrication. Electrodeposition, a practical treatise on the electrolysis of gold, silver, copper, nickel, and other metals, and alloys. The operator clamps the production panels into the jigs. Copper electrodeposition from a copper acid baths in the presence.
Brake wear from vehicles as an important source of diffuse copper. Pdms replica with silver, an electroless deposition method was used. Cuni was formed via deposition of copper utilizing a solution from a previous electroless deposition study onto freshly templated and subsequently rinsed nickel nanonetworks. In general, electroless plating is characterized by the selective reduction of metal ions only at the surface of a catalytic substrate immersed into an aqueous solution of said metal ions, with continued deposition on the substrate through the catalytic action of the deposit itself. The main advantage electroless copper plating is widely used for the fabrication of printed circuit boards and other electronic devices. Koc adepartment of chemical and environmental engineering, national university of singapore, 10 kent ridge crescent, singapore 119260. For example, the electroless copper solution using hypophosphite as the.
Electroless copper is being investigated for seed layer repair in high aspect ratio features, as a low cost method of seed layer deposition 1 and as an alternative to electrolytic copper in the interconnect line and via deposition 2,3. In electroless deposition, partial oxidation and reduction reactions occur at the same electrode surface. Vorobyova electroless deposition and electroplating of metals introduction alongside with multipurpose procedures of lowtemperature metal deposition by electrochemical reduction of their. This activation step must precede immediately before the copper deposition. Electroless copper plating, however, offers advantages over electrolytic plating that make it the method of choice in certain cases. Also, in 1962, brookshire in his us patent 3,046,159 method of copper plating by chemical reduction 84 used an insoluble compound of copper in the reduction plating solution. A continuous copper deposition could be obtained as the nickel ion concentration and temperature were more than 0. A high reliability, stressfree copper deposit for fpc. However, the small size and large specific surface area intrinsically associated with acs pose challenges in the synthesis and stabilization of ptacs without agglomeration. Electroless copper plating is widely used for the fabrication of printed circuit boards and other electronic devices. Oxidationstable cu nanoparticles and nanowires were prepared in aqueous solution in the presence of protective agents.
Copper layers were electrolessly deposited on the surface of carbon fiber without using the conventional palladium or silver catalyst to initiate redox reactions leading to metallization. Examination of the effect of ultrasound on electroless. Electroless, or autocatalytic, metal plating is a non electrolytic method of deposition from solution. An electrochemical investigation of electroless deposition. Electroless deposition is similar to electroplating but can be done without the need for an external current. Electroless copper deposition from solutions containing dmannitol as the cuii ligand according to a recent investigation of equilibria in. Experimental investigated tin coatings were deposited on the copper foil m1e in the immersion process. Comparison and characterization of copper precursors cu thin. The area inside the dotted liner indicater the range of valuer within which variour copper ions are thermodynamically rtabie. The minimum necessary components of an electroless. A new bath for electroless copper deposition over pcb was made using copper methane sulfonate as a source of metal ion which has excellent solubility than copper sulfate. Copper methane sulphonate, stable bath, saccharose, thiourea introduction provide a seed layer on a dielectric material for subsequent acid copper electroplating12. The first step in the plating process is the chemical deposition of a very thin layer of copper on the hole walls. However, until now a big discrepancy exist between atmospheric deposition.
Pt atomic clusters ptacs display outstanding electrocatalytic performance because of their unique electronic structure with a large number of highly exposed surface atoms. When an iron substrate is immersed in a solution of copper sulfate or silver nitrate, the iron dissolves while the copper or silver is plated out onto the surface. Electroless copper in printed wiring board fabrication 335 fig. Electroless deposition of copper nanostructures in aqueous. The redox potential for the oxidation half reaction becomes more negative when the ph of the electroless deposition solution is increased. A discussion started in 2001 but continuing through 2017.
This paper describes metallization of pet surface by snfree electroless deposition eld of thin copper layer. The solderability of immersion sn coatings is also compared. Copper hydride, cuh, has been shown by in situ xray diffraction method to form in the process of electroless copper deposition in alkaline solutions containing cuii complexes with tartrate and. Pdf electroless deposition of copper in acidic solutions. Electroless cu plating microelectronics applications. In spite of very slow developments throughout the centuries, significant scientific results have been achieved in.
The growth of graphene during cucatalyzed chemical vapor deposition was studied. A study on the interfacial composition of the electroless. Chapter 12 fundamental aspects of electroless copper plating tau. A study on the interfacial composition of the electrolesscopperplated bpdapda polyimide sheet w. Can anybody tell me the formula for electroless copper. Eld is a multistep process involving silanization with tms, activation with pdcl2 and copper deposition. Electroless copper plates uniformly over all surfaces, regardless of size and shape. This article introduces a new technique of electroless copper deposition on carbon fibers in the absence of precious metal as the catalyst. It is mainly different from electroplating by not using external electrical power applications plated through holes. Electroless copper deposition using saccharose containing.
The line is fully computer controlled and the panels are carried through a series of. Electrolytic removal of cu was studied at different initial ph ph o values when the nominal initial concentration of copper ions was held constant. Electroless deposition or plating is a nongalvanic plating method that does not require any external electrical power. Hanb acapst and department of chemistry, sungkyunkwan university, suwon 440746, south korea bcapst and department of metallurgical engineering, sungkyunkwan university, suwon 440746, south korea. Thin and continuous copper films serve as seed layers for electrodeposition.
Journal of the electrochemical society, c787 004651. In chronoamperometry experiments, the potential was stepped from the opencircuit potential to the potential at which the deposition of copper would occur. A precious metalfree electroless technique for the. Electroless deposition is a process that has been used in practice for centuries. This new technique shows that nickel seeds can serve as excellent. A new electroless plating process for cu and cup alloys. Pdf electroless deposition ed of copper coating on. Electroless deposition of copper modern electroplating. Journal of the electrochemical society c631c636 c631 00.
Naoh is used to increase the reducing power of hcho. The deposition rate increased obviously with the increase of temperature, ph and nickel ion. Electrodeposition of copper from a copper sulfate solution. The electroless copper plating using sodium hypophosphite as the reductant and sodium citrate as the chelating agent was studied by gravimetric. For deposition to occur, the redox potential of the reducing agent has to be more negative than that for the metal being deposited. Riddell, electroless plating involves the deposition of such metals as copper, nickel, silver, gold, or palladium on the surface of a variety of materials by means of a reducing chemical bath. Electrochemical ald enables the atomicallyprecise deposition of cu films. Diffusion study of electrodeposited coppernickel multilayer core. In the case of sulfate solution the copper deposition peak and the onset of hydrogen evolution overlap. A discussion started in 2005 but continuing through 2016 and beyond.
The copper deposition on activator layer is carried out by dipping the substrate. Electroless copper plating an overview sciencedirect. The diameter of the wire after deposition should be constant over the. Electroless plating, nonelectrical plating of metals and plastics to achieve uniform coatings by a process of controlled autocatalytic selfcontinuing reduction. Thin, continuous, and conformal copper films by reduction of. It is effective because it can deposit silver on both conductive and nonconductive materials, such as polymers. Formation of cu nanoparticles by electroless deposition of cu. This suggests that at elevated temperatures and higher phs, copper surface passivation is accelerated.
Electroless copper plates much more slowly, and is a much more expensive process, than electrolytic copper plating. One way to compensate for the poor catalytic activity of copper is to add nickel ions to the solution 5152. Carbondefectdriven electroless deposition of pt atomic. Highrate deposition of copper thin films using newly designed highpower magnetron sputtering source jinhyo booa, min jae jungb, heon kyu parkb, kyung hoon namb, jeon g. For copper deposition, a freshly prepared bath having 0. Previously used precursors have not demonstrated reactivity to molecularreducing agents at low temperatures. The onset of the reduction of copper occurs at much lower overpotentials for acidic than alkaline solutions. In this i have the problem that i should cover a steel wire of a few millimeters diameter with copper. Electroless deposition ed of copper coating on micronsized sic particles article pdf available in surface engineering 3010. The control of graphene doublelayer formation in copper. The bath was optimized for metal ion concentration, ph of the.
Thin layer of metal oxides on glass substrate using electroless deposition on free shipping on qualified orders. Pollution prevention technology profile trivalent chromium replacements for hexavalent chromium plating pdf. Zhu 7, schneider and their coresearchers8 investigated the electroless copper plating process using sulphur compounds as additives and found that the compounds enhanced the plating rate. Chapter 12 fundamental aspects of electroless copper plating. Contact angle measurement and xps analysis were carried out at each stage in. Although not recognized as such, electroless deposition of noble metals, e. Macdermid enthone mcopper 15 is the thin deposition electroless copper developed specifically for fabricators that require process flexibility and reduced overall chemical costs in the development of their super thick circuit boards mcopper 15, able to plate 15 microinches in 15 minutes, is impervious to bath loading and can be utilized in either basket mode or 1up inline for ultimate. In particular, electroless copper deposition, the most commonly used method of metallizing a nonconductive substrate, is susceptible to blistering or peeling due to the low adhesion of the copper film to the substrate. Visually, slight copper deposition was noticed after 90 seconds. Electroless plating, also known as chemical or autocatalytic plating, is a nongalvanic plating method that involves several simultaneous reactions in an aqueous solution, which occur without the use of external electrical power. Study of coppersilicon junctions fabricated by selective. Electrochemical control system for electroless copper deposition.
Highrate deposition of copper thin films using newly. This paper reports a simple and low cost process for the synthesis of various cu nanostructures by electroless deposition. Formaldehyde free ecofriendly novel bath for electroless. Since adherent nickel deposit cannot be deposited directly from. This shows that silica nanoparticles increase the adhesion between the copper film and the fig. Deposition of electroless copper for ic abrication. Environmentally friendly natural polyhydroxylic compounds. Electroless copper plating on pet fabrics using hypophosphite as reducing agent was investigated. The copper deposition peak is immediately followed by the onset of hydrogen evolution.
The bath consists of copper methane sulfonate, edta, glyoxylic acid and naoh to raise the ph. Synthesis of graphene films on copper foils by chemical vapor. Electroplating is a process that uses an electric current to reduce dissolved metal cations so. Electroless copper deposition on pet sheets scientific. The layer is obtained by electroless deposition of copper from a reducible copper solution on a nonconductive body such as paper. The codeposited nickel in the copper deposit serves to catalyze the oxidation of hypophosphite, thus increasing the overall deposition rate 53. Electroless copper can provide a seed layer on a dielectric material for subsequent acid copper electroplating.
259 791 1213 1166 1390 941 1367 725 766 1510 294 979 1474 853 893 374 1178 375 140 873 628 1116 304 1338 195 362 1491 981 1057 668 131 1294 1405 415 148 1065 618 211 628 512